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CBSE Notes | Class 12th | Chemistry Part 2 | NCERT Based :Hoffmann bromamide degradation reaction

Submitted by admin (not verified) on Thu, 12/01/2011 - 12:02

Hoffmann bromamide degradation reaction

Hoffmann developed a method for preparation of primary amines by treating an amide with bromine in an aqueous or ethanolic solution of sodium hydroxide. In this degradation reaction, migration of an alkyl or aryl group takes place from carbonyl carbon of the amide to the nitrogen atom. The amine so formed contains one carbon less than that present in the amide.

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